冈底斯中段容果地区二长花岗岩锆石U-Pb年龄及其地球化学特征     

胡林  徐刚  刘大明 《中国地质调查》2020,7(4):67-75

为确定容果地区二长花岗岩的形成时代、成因及其地质意义,对容果地区二长花岗岩进行了岩相学、LA-ICP-MS锆石U-Pb年龄及地球化学研究。结果表明: 二长花岗岩中的锆石为岩浆成因,²⁰⁶Pb/²³⁸U年龄加权平均值为(69±1) Ma,侵入时代属于晚白垩世; 二长花岗岩中Al₂O₃含量为13.83%~14.41%,Na₂O含量为3.68%~3.94%,K₂O含量为4.28%~4.35%, K₂O/Na₂O为1.08~1.18,相对富钾,铝饱和指数A/CNK平均为1.02,属弱过铝质岩石; 微量元素特征表现为相对富集Rb、U、K等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素的特征。结合区域构造演化背景,可得出在80~69 Ma之间,该区的岩浆活动并未停止,仍然持续在发生,所生成的岩体是新特提斯洋壳俯冲的岩浆产物,形成于造山环境下,形成过程贯穿整个造山运动。  相似文献   

印度河上游Bagrot山谷降水稳定同位素变化及与水汽来源的关系          下载免费PDF全文

王邺凡  余武生  张寅生  张腾  高海峰  MUHAMMAD Atif Wazir 《干旱区地理》2019,42(2):252-262

利用2015年8月至2016年7月在印度河上游流域Bagrot山谷降水稳定同位素（δ18O和δD）观测结果以及当地气象资料，利用同位素示踪及统计分析方法，并结合HYSPLIT模型，对研究区降水稳定同位素变化特征、大气水线以及水汽来源进行了分析。结果表明，观测期间Bagrot山谷降水稳定同位素的季节变化明显，δ18O与δD秋冬季偏低，春夏季偏高，且与气温变化一致，存在显著的温度效应，而降水量效应不明显。而且发现，研究区局地大气水线截距和斜率均低于全球的，反映了降水过程中云下二次蒸发作用较为强烈，特别是，不同的降水形态导致该研究区局地大气水线的斜率和截距不同。当液态降水（降雨）发生时，由于在较为干旱的气候环境下，雨滴在降落的过程中受到二次蒸发相对较强，使得局地大气水线的斜率和截距偏低；而当固态降水（降雪）发生时，由于温度较低，受再循环水汽和二次蒸发的影响较小，导致局地大气水线的斜率和截距均偏高。Bagrot山谷及其周边地区，从南到北局地大气水线的斜率相差不大，而其截距总体上随着纬度升高而降低，可能与云下二次蒸发导致稳定同位素发生的不平衡分馏逐渐强烈有关。通过Bagrot山谷站点降水稳定同位素观测结果并结合HYSPLIT模型的后向追踪，研究还发现，研究区全年主要受西风环流以及局地环流的影响。但与研究区以北的临近站点（慕士塔格、和田等）相比有所不同，由于Bagrot山谷位置更靠南，其仍然偶尔受到来自南方的海洋性水汽影响。这一研究结果可能对该地区树轮稳定同位素记录的解译具有一定的指示意义。  相似文献   

Bound and mobile soil water isotope ratios are affected by soil texture and mineralogy,whereas extraction method influences their measurement     

Rachel E. Adams  Ayumi Hyodo  Toby SantaMaria  Cynthia L. Wright  Thomas W. Boutton  Jason B. West 《水文研究》2020,34(4):991-1003

Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ²H and δ¹⁸O of soil water isotope ratios.  相似文献   

安徽黄梅尖地区基性岩脉K-Ar年代学、地球化学特征及地质意义          下载免费PDF全文

杨彪  王正其  肖金根  曹达旺 《华东地质》2020,(1):27-35

在野外地质调查和室内综合研究的基础上,通过对黄梅尖地区辉绿玢岩K-Ar年代学、地球化学和Sr-Nd同位素特征进行研究,探讨辉绿玢岩的形成时代、岩石成因及构造背景。K-Ar年代学研究表明,辉绿玢岩形成于~107 Ma,是早白垩世岩浆活动的产物,形成时代晚于该地区火山岩和侵入岩,与该地区铀成矿年龄基本一致;辉绿玢岩的侵入可能是该地区岩浆作用的最后一幕,铀成矿可能与辉绿玢岩具有成因联系。地球化学特征表明,辉绿玢岩富集大离子亲石元素K、Rb、U、Pb和轻稀土元素,亏损高场强元素Nb、Ta、P、Ti,具有较高的Isr值和负εNd(t)值,具有富集地幔源区特征;辉绿玢岩是在地壳伸展和岩石圈减薄的构造背景下,由俯冲交代作用形成的富集地幔部分熔融形成的,表明~107 Ma时该地区仍处于伸展构造环境下。  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Assessing basin storage: Comparison of hydrometric- and tracer-based indices of dynamic and total storage     

Ciara D. Cooke  James M. Buttle 《水文研究》2020,34(9):2012-2031

Storage is a fundamental but elusive component of drainage basin function, influencing synchronization between precipitation input and streamflow output and mediating basin sensitivity to climate and land use/land cover (LULC) change. We compare hydrometric and isotopic approaches to estimate indices of dynamic and total basin storage, respectively, and assess inter-basin differences in these indices across the Oak Ridges Moraine (ORM) region of southern Ontario, Canada. Dynamic storage indices for the 20 study basins included the ratio of baseflow to total streamflow (baseflow index BFI), Q ₉₉ flow and flow duration curve (FDC) slope. Ratios of the standard deviation of the streamflow stable isotope signal relative to that of precipitation were determined for each basin from a 1 year bi-weekly sampling program and used as indicators of total storage. Smaller ratios imply longer water travel times, smaller young water fractions (F _yw, < ~2–3 months in age) in streamflow and greater basin storage. Ratios were inversely related to BFI and Q ₉₉, and positively related to FDC slope, suggesting longer travel times and smaller F _yw for basins with stable baseflow-dominated streamflow regimes. Inter-basin differences in all indices reflected topographic, hydrogeologic and LULC controls on storage, which was greatest in steep, forest-covered headwaters underlain by permeable deposits with thick and relatively uniform unsaturated zones. Nevertheless, differential sensitivity of indices to controls on storage indicates the value of using several indices to capture more completely how basin characteristics influence storage. Regression relationships between storage indices and basin characteristics provided reasonable predictions of aspects of the streamflow regime of test basins in the ORM region. Such relationships and the underlying knowledge of controls on basin storage in this landscape provide the foundation for initial predictions of relative differences in streamflow response to regional changes in climate and LULC.  相似文献   

辽北开原地区房木花岗斑岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

豆世勇 《吉林大学学报(地球科学版)》2020,50(6):1752-1765

研究区位于华北克拉通北缘东段、华北克拉通与兴蒙造山带的交接部位。本文通过对辽北开原地区房木花岗斑岩的岩石学、年代学和地球化学研究，探讨了其形成时代、岩石成因和构造环境，并进一步探讨了华北克拉通东部岩石圈减薄的起始时间。用LA-ICP-MS技术测定了花岗斑岩的锆石U-Pb同位素，获得其锆石²⁰⁶Pb/²³⁸U加权平均年龄为（117±1）Ma，表明花岗斑岩形成于早白垩世。花岗斑岩具有高硅、富碱、贫镁和钙的特征，富集大离子亲石元素（K、Rb）和高场强元素（Th、Ta、Nb），亏损Sr、Ba、P、Ti元素，稀土配分曲线均呈现右倾海鸥型，具有明显的负Eu异常；显示研究区花岗斑岩为A型（A₁亚型）花岗岩，形成于古太平洋俯冲的后造山伸展环境，其岩浆源于地幔物质上涌而导致的地壳物质重熔。研究区在（156±1）Ma之前，属于挤压造山环境，表明研究区岩石圈减薄时间应处于156~117 Ma之间。  相似文献   

滇中禄丰地区中元古代早期球颗玄武岩的锆石U-Pb年龄、地球化学特征及其大地构造意义     

刘军平  孙柏东  王晓峰  刘伟  马进华  关学卿  宋冬虎  吕勃烨 《地质论评》2020,66(1):35-51

在1∶5万区域地质调查的基础上,在禄丰地区东川群黑山组新发现了球颗玄武岩及凝灰岩夹层。采用LA-ICP-MS技术测得球颗玄武岩和凝灰质板岩中锆石U-Pb加权平均年龄分别为1678±10 Ma和1572±19 Ma,表明黑山组沉积时代为中元古代早期;其中球颗玄武岩SiO_2含量介于40.83%～52.56%,δEu正异常,大离子亲石元素Rb、Ba和高场强元素Nb、Ta、Th等强不相容元素相对富集,全岩地球化学显示为大陆板内低钛拉斑海相玄武岩,形成于伸展的构造环境,可能为Columbia超大陆裂解的产物。本次的发现,为准确地标定东川群时代、层序及大地构造属性提供新的参考依据,也为重塑整个滇中前寒武纪地层格架提供时代约束。  相似文献   

华北板块北缘勃隆克A型花岗岩锆石U-Pb定年及其地质意义     

李春麟  王宗秀  陶涛 《地质通报》2020,(1):40-50

内蒙古翁牛特旗勃隆克岩体位于华北板块北缘,侵位于上侏罗系火山岩地层中。详细的岩相学研究显示,勃隆克花岗岩具有粒状结构、蠕虫结构和文像结构,块状构造,部分斜长石已绢云母化、泥化。对勃隆克花岗岩进行了LA-ICP-MS锆石U-Pb定年,获得134.0±1.8Ma和134.9±4.1Ma的侵位年龄,表明其形成于早白垩世。地球化学特征显示,花岗岩属于高钾钙碱性系列,有较高的SO2(74.1%~75.6%)、Na2O+K2O(8.98%~9.2%)、Rb(210×10-6~225×10-6)含量和10000×Ga/Al(2.69~2.80)、Rb/Sr(5.8~18.9)值,具有较低的CaO、MgO、Ba和Sr含量。铝饱和指数A/CNK=0.99~1.03,属于偏铝质或过铝质A型花岗岩。稀土元素球粒陨石标准化图解显示,轻稀土元素相对富集,负Eu异常明显;在原始地幔标准化图解上,Ba、Sr、Nb、Ta、P、T强烈亏损,富集Rb、Th、K、Hf等元素,与华北板块北缘早白垩世A型花岗岩类似。结合区域构造演化,认为勃隆克花岗岩形成于伸展构造背景。晚中生代,华北板块北缘构造体制经历了重大的转变,地壳从挤压体制转为岩石圈减薄和地壳伸展体制,软流圈物质上涌导致上覆地壳长英质物质的部分熔融形成勃隆克A型花岗岩。  相似文献   

内陆水体溶解无机碳同位素研究进展及展望     

范美彤  葛璐  谭红兵  陈维 《地质论评》2020,66(6):1637-1648

碳是陆地生态系统中最重要的生命元素，能够在各个圈层之间相互转换和运移。碳循环作为地球各圈层相互连接的纽带，被认为是地表系统最重要的元素地球化学循环。碳在水体中主要以溶解性有机碳（dissolved organic carbon，简称DOC）和溶解性无机碳（dissolved inorganic carbon，简称DIC）形式存在。内陆水体（包括河水、地下水、湖水和水库等）尽管只占陆地表面1%，但它们在碳循环过程中发挥了重要作用。其DIC浓度(CDIC)和DIC同位素组成(δ13CDIC)可以为碳循环研究提供线索，因此成为近年来国际研究的热点之一。本文系统总结了全球内陆水体DIC同位素的研究进展。DIC同位素具有广泛的地质应用，不同碳源具有独特的同位素特征。因此，DIC同位素被用于定性和定量地示踪碳源，指示碳循环过程以及确定河水补给端元。  相似文献